Friday, April28, 2017 L-36.com

Corrosion Control - Galvanic Tables



Index

Note that there are several tables presented on this page and that they do not all agree. These have been collected from various sources and I list them all so you can judge for yourself the variation in the literature. If you are measuring your boat to see if it has the hull potential it should, I suggest you use a zinc reference and look for 0 volts as that is the goal. That leaves aside the calibration problem as zinc to zinc is 0 volts no matter how you define the reference.

Galvanic Potential

The table below reports the Corrosion potentials or Galvanic Series of metals in flowing sea water at ambient temperature.

The unshaded symbols show ranges exhibited by stainless steels in acidic water such as may exist in crevices or in stagnant or low velocity or poorly aerated water where Stainless Steel become active, while the shaded areas show the potentials of Stainless Steel when is in passive state. corrosion

Galvanic Series In Flowing Sea Water

Steady State Electrode Material Potential, Volts referenced to Saturated Calumel Half-Cell
Graphite +0.25
Platinum +0.15
Zirconium 0.04
Type 316 Stainless Steel (Passive) 0.05
Type 304 Stainless Steel (Passive) 0.08
Monel 400 0.08
Hastelloy C 0.08
Titanium 0.1
Silver 0.13
Type 410 Stainless Steel (Passive) 0.15
Type 316 Stainless Steel (Active) 0.18
Nickel 0.2
Type 430 Stainless Steel (Passive) 0.22
Copper Alloy 715 (70-30 Cupro-Nickel) 0.25
Copper Alloy 706 (90-10 Cupro-Nickel) 0.28
Copper Alloy 443 (Admiralty Brass) 0.29
G Bronze 0.31
Copper Alloy 687 (Aluminum Brass) 0.32
Copper 0.36
Alloy 464 (Naval Rolled Brass) 0.4
Type 410 Stainless Steel (Active) 0.52
Type 304 Stainless Steel (Active) 0.53
Type 430 Stainless Steel (Active) 0.57
Carbon Steel 0.61
Cast Iron 0.61
Aluminum 3003-H 0.79
Zinc 1.03
As long as titanium remains passive, it will be galvanically protected by any material below it (less noble) in the galvanic series. The farther apart in the series, the greater the rate of attack on the less noble metal. While the sea water series is a good guide, behavior in other environments may be different, so care should be exercised when dissimilar couples are to be utilized. A smaller relative area of the corroding (less noble) metal will result in accelerated metal loss because the smaller area must provide a higher corrosion current density to protect the larger area. Under galvanic conditions, hydrogen evolves at the titanium (cathode) surface and may be galvanically charged in to the titanium where the potential difference is 0.75 volts or greater, if temperatures are above 80 o C (176 o F), pH is low (>3), and the titanium surface is breached (by iron) or damaged by abrasion. If titanium becomes active, for example in a reducing acidic environment, the protective surface oxide may be destroyed, titanium's galvanic behavior more like aluminum, and titanium may suffer loss of metal. In couples with stainless steel, there is a strong possibility that the stainless steel will become active.

Galvanic Table from MIL-STD-889.

Listed below is the latest galvanic table from MIL-STD-889. For any combination of dissimilar metals, the metal with the lower number will act as an anode and will corrode preferentially.

The table is the galvanic series of metals in sea water from Army Missile Command Report RS-TR-67-11, "Practical Galvanic Series."

The Galvanic Table

Active (Anodic)

  1. Magnesium
  2. Mg alloy AZ-31B
  3. Mg alloy HK-31A
  4. Zinc (hot-dip, die cast, or plated)
  5. Beryllium (hot pressed)
  6. Al 7072 clad on 7075
  7. Al 2014-T3
  8. Al 1160-H14
  9. Al 7079-T6
  10. Cadmium (plated)
  11. Uranium
  12. Al 218 (die cast)
  13. Al 5052-0
  14. Al 5052-H12
  15. Al 5456-0, H353
  16. Al 5052-H32
  17. Al 1100-0
  18. Al 3003-H25
  19. Al 6061-T6
  20. Al A360 (die cast)
  21. Al 7075-T6
  22. Al 6061-0
  23. Indium
  24. Al 2014-0
  25. Al 2024-T4
  26. Al 5052-H16
  27. Tin (plated)
  28. Stainless steel 430 (active)
  29. Lead
  30. Steel 1010
  31. Iron (cast)
  32. Stainless steel 410 (active)
  33. Copper (plated, cast, or wrought)
  34. Nickel (plated)
  35. Chromium (Plated)
  36. Tantalum
  37. AM350 (active)
  38. Stainless steel 310 (active)
  39. Stainless steel 301 (active)
  40. Stainless steel 304 (active)
  41. Stainless steel 430 (active)
  42. Stainless steel 410 (active)
  43. Stainless steel 17-7PH (active)
  44. Tungsten
  45. Niobium (columbium) 1% Zr
  46. Brass, Yellow, 268
  47. Uranium 8% Mo.
  48. Brass, Naval, 464
  49. Yellow Brass
  50. Muntz Metal 280
  51. Brass (plated)
  52. Nickel-silver (18% Ni)
  53. Stainless steel 316L (active)
  54. Bronze 220
  55. Copper 110
  56. Red Brass
  57. Stainless steel 347 (active)
  58. Molybdenum, Commercial pure
  59. Copper-nickel 715
  60. Admiralty brass
  61. Stainless steel 202 (active)
  62. Bronze, Phosphor 534 (B-1)
  63. Monel 400
  64. Stainless steel 201 (active)
  65. Carpenter 20 (active)
  66. Stainless steel 321 (active)
  67. Stainless steel 316 (active)
  68. Stainless steel 309 (active)
  69. Stainless steel 17-7PH (passive)
  70. Silicone Bronze 655
  71. Stainless steel 304 (passive)
  72. Stainless steel 301 (passive)
  73. Stainless steel 321 (passive)
  74. Stainless steel 201 (passive)
  75. Stainless steel 286 (passive)
  76. Stainless steel 316L (passive)
  77. AM355 (active)
  78. Stainless steel 202 (passive)
  79. Carpenter 20 (passive)
  80. AM355 (passive)
  81. A286 (passive)
  82. Titanium 5A1, 2.5 Sn
  83. Titanium 13V, 11Cr, 3Al (annealed)
  84. Titanium 6Al, 4V (solution treated and aged)
  85. Titanium 6Al, 4V (anneal)
  86. Titanium 8Mn
  87. Titanium 13V, 11Cr 3Al (solution heat treated and aged)
  88. Titanium 75A
  89. AM350 (passive)
  90. Silver
  91. Gold
  92. Graphite
End - Noble (Less Active, Cathodic)

Galvanic Voltages relative to Gold

To determine the potential of a battery, take the difference between the numbers for the two metals that make up the battery from this table.
MetallurgyIndex (V)
Gold, solid and plated, Gold-platinum alloy0.00
Rhodium plated on silver-plated copper0.05
Silver, solid or plated; monel metal. High nickel-copper alloys0.15
Nickel, solid or plated, titanium an s alloys, Monel0.30
Copper, solid or plated; low brasses or bronzes; silver solder; German silvery high copper-nickel alloys; nickel-chromium alloys0.35
Brass and bronzes0.40
High brasses and bronzes0.45
18% chromium type corrosion-resistant steels0.50
Chromium plated; tin plated; 12% chromium type corrosion-resistant steels0.60
Tin-plate; tin-lead solder0.65
Lead, solid or plated; high lead alloys0.70
Aluminum, wrought alloys of the 2000 Series0.75
Iron, wrought, gray or malleable, plain carbon and low alloy steels0.85
Aluminum, wrought alloys other than 2000 Series aluminum, cast alloys of the silicon type0.90
Aluminum, cast alloys other than silicon type, cadmium, plated and chromate0.95
Hot-dip-zinc plate; galvanized steel1.20
Zinc, wrought; zinc-base die-casting alloys; zinc plated1.25
Magnesium & magnesium-base alloys, cast or wrought1.75
Beryllium1.85

Galvanic Voltage relative to standard electrode


Short Table

ANODIC (Least Noble)
Magnesium
Zinc
Aluminium
Carbon steel or cast iron
Copper alloys (brass, bronze )
Lead
STAINLESS STEEL
Nickel alloys (Incoloy 825,Hastelloy B)
Titanium
Graphite
CATHODIC (Most Noble)

When is stainless steel passive or active - formation of the passive layer

The inherent corrosion resistance of stainless steels is derived from alloying the base iron with chromium. BS EN 10088-1 states that a steel must have a minimum of 10.5% (by weight) chromium and a maximum of 1.2% carbon to be classified as 'stainless'. Other alloying elements including nickel, molybdenum, nitrogen, titanium (or niobium) are added to form the various grades. These additions are made to enhance the 'basic' corrosion resistance of the steel but can also usefully modify other properties, such as formability, strength and cryogenic toughness. The corrosion resistance of stainless steel arises from a 'passive', chromium-rich, oxide film that forms naturally on the surface of the steel. Although extremely thin at 1-5 nanometres (i.e. 1-5 x 10-9 metres) thick, this protective film is strongly adherent, and chemically stable (i.e. passive) under conditions which provide sufficient oxygen to the surface. This 'normal' condition is the passive state. The key to the durability of the corrosion resistance of stainless steels is that if the film is damaged it will normally self repair (provided there is sufficient oxygen available). However, under certain conditions, the passive state can be broken down, resulting in corrosive attack.If damaged, the film will normally repair itself. If the film is destroyed the surface is said to be in the active state.

Discussion on Galvanic Table (Almost straight from MIL-STD-889)

AC43.13, starting at Par 247, briefly covers several types of corrosion and corrosion protection. The grouping of materials is an early method of MS33586 which was superseded in 1969 by MIL-STD-889.

General

The Galvanic Table lists metals in the order of their relative activity in sea water environment. The list begins with the more active (anodic) metal and proceeds down the to the least active (cathodic) metal of the galvanic series.

A "galvanic series" applies to a particular electrolyte solution; hence for each specific solution which is expected to be encountered for actual use, a different order or series will ensue. The sea water galvanic series is the most complete series that I know and I have not seen another series published by either the Army, Navy, or Air Force. Civilian aircraft encounter moisture and a salt of some kind.

Galvanic series relationships are useful as a guide for selecting metals to be joined, will help the selection of metals having minimal tendency to interact galvanically, or will indicate the need or degree of protection to be applied to lessen the expected potential interactions.

Generally, the closer one metal is to another in the series, the more compatible they will be, i.e., the galvanic effects will be minimal. Conversely, the farther one metal is from another, the greater the corrosion will be.

Notice that graphite is at the bottom of the table. Think of the corrosion potential if you put a big hunk of graphite on a small piece of magnesium.

In a galvanic couple, the metal higher in the series (or the smaller the number I have given it) represents the anode, and will corrode preferentially in the environment.

Types of Protection

Metals widely separated in the galvanic series must be protected if they are to be joined. Appropriate measures should be taken to avoid contact. This can be accomplished by several methods:
  1. Sacrificial - by applying to the cathodic member a sacrificial coating having a potential similar to or near that of the anodic member. If you are designing for a sacrificial element, the sacrificial element should be on the anodic side and smaller. Cadmium plate (No. 10) on steel bolts (No. 81) holding 2024-T4 (No. 25) plates will sacrifice the cadmium instead of corroding the Aluminum. This is one reason for using new bolts that have the Cad plate intact. (Don't use Cad plate with Titanium (No. 82 through 88). But that's another story.)
  2. Sealing - by sealing to insure that faying surfaces are water-tight. (We have "talked" about this before.)
  3. Resistance - by painting or coating all surfaces to increase the resistance of the electrical circuit. (We have "talked" about this only in terms of primer and sealant on fayed surfaces. There is still more that can be done by design selection.)

The (Non-Aerodynamic) Area Rule

To avoid corrosion, avoid a small anodic area relative to the cathodic area.

Corollary I - Use LARGE ANODE AREA.

Corollary II - The larger the relative anode area, the lower the galvanic current density on the anode, the lesser the attack.

Corollary III - The amount of galvanic corrosion may be considered as proportional to the Cathode/Anode area ratio.

Corollary IV - Design for a SMALL Cathodic/Anodic Ratio (CAR). (When designing, remember your small CAR.)

Corollary V - The same metal or more noble (cathodic, higher number in the table) metals should be used for small fasteners and bolts.

Sea Water Environments

Metals exposed to sea water environments shall be corrosion and stress corrosion resistant or shall be processed to resist corrosion and stress-corrosion. Irrespective of metals involved, all exposed edges should be sealed with a suitable sealant material conforming to MIL-S-8802. When non-compatible materials are joined, an interposing material compatible with each shall be used.

Non-Metallic Materials

Material other than true metals, i.e., non-metallic materials which must be considered as metallic materials, unless there is supporting evidence to the contrary. If these material are essentially free of corrosive agents (salts), free of acid or alkaline materials (neutral pH), and free of carbon or metallic particles, not subject to biodeterioration or will not support fungal growth, and do not absorb or wick water, then these may be considered non-metallics suitable for joining to metals.

Many materials classed non-metallic will initiate corrosion of metals to which they are joined, e.g., cellulosic reinforced plastics, carbon or metal loaded resin materials, asbestos-cement composites.

More Precautions for Joining

Where it becomes necessary that relatively incompatible metals must be assembled, the following precautions and joining methods are provided for alleviation of galvanic corrosion.

For Electrical Connection - Select materials which are indicated to be more compatible in accordance with the galvanic series.

Design metal couples so that the area of the cathode is smaller (appreciably) than the area of the anodic metal. For example, bolts or screws of stainless steel for fastening aluminum sheet, but not reverse.

Interpose a compatible metallic gasket or washer between the dissimilar metals prior to fastening.

Plate the cathodic member with a metal compatible to the anode.

Select a electrically conductive sealant. (More on these later.)

Not For Electrical Conductors - Interpose a non-absorbing, inert gasket material or washer between the dissimilar materials prior to connecting them.

Other Approaches

Seal all faying edges to preclude the entrance of liquids.

Apply corrosion-inhibiting pastes or compounds under heads of screws or bolts inserted into dissimilar metal surfaces whether or not the fasteners had been previously plated or otherwise treated. In some instances, it may be feasible to apply an organic coating to the faying surfaces prior to assembly. This would be applicable to joints which are not required to be electrically conductive.

Where practicable or where it will not interfere with the proposed use of the assembly, the external joint should be coated externally with an effective paint system.


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The information on this web site has not been checked for accuracy. It is for entertainment purposes only and should be independently verified before using for any other reason. There are five sources. 1) Documents and manuals from a variety of sources. These have not been checked for accuracy and in many cases have not even been read by anyone associated with L-36.com. I have no idea of they are useful or accurate, I leave that to the reader. 2) Articles others have written and submitted. If you have questions on these, please contact the author. 3) Articles that represent my personal opinions. These are intended to promote thought and for entertainment. These are not intended to be fact, they are my opinions. 4) Small programs that generate result presented on a web page. Like any computer program, these may and in some cases do have errors. Almost all of these also make simplifying assumptions so they are not totally accurate even if there are no errors. Please verify all results. 5) Weather information is from numerious of sources and is presented automatically. It is not checked for accuracy either by anyone at L-36.com or by the source which is typically the US Government. See the NOAA web site for their disclaimer. Finally, tide and current data on this site is from 2007 and 2008 data bases, which may contain even older data. Changes in harbors due to building or dredging change tides and currents and for that reason many of the locations presented are no longer supported by newer data bases. For example, there is very little tidal current data in newer data bases so current data is likely wrong to some extent. This data is NOT FOR NAVIGATION. See the XTide disclaimer for details. In addition, tide and current are influenced by storms, river flow, and other factors beyond the ability of any predictive program.